Atomic Structure of Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets
نویسندگان
چکیده
منابع مشابه
Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization.
Single-unit-cell Sn-MFI, with the detectable Sn uniformly distributed and exclusively located at framework sites, is reported for the first time. The direct, single-step, synthesis is based on repetitive branching caused by rotational intergrowths of single-unit-cell lamellae. The self-pillared, meso- and microporous zeolite is an active and selective catalyst for sugar isomerization. High yiel...
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Ultrathin MFI-zeolite nanosheets can be packed on porous supports to create molecular sieve membranes. The nanosheets on porous support reduce morphological damage seen in regular MFIzeolite crystals [1]. MFI-zeolite belongs to pentasil family of zeolites where the periodic building unit (PerBU) is composed of 12 interconnected SiO4 tetrahedral (T12) units of 41m2 (D2d) symmetry [2]. Rotation o...
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Self-pillared pentasil (SPP) zeolite is a hierarchically-structured zeolite comprised of single-unit cell thick MFI nanosheets arranged in a ‘‘house of cards’’ structure. The nucleation and growth of SPP proceeds through three phases involving the evolution of precursor amorphous nanoparticles to MFI nanosheets and then rotational intergrowth of sheets to produce the SPP morphology. This paper ...
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Stable suspensions of zeolite nanosheets (3 nm thick MFI layers) were prepared in ethanol following acid treatment, which partially removed the associated organic structure-directing agent. Nanosheets from these suspensions could then be dispersed at the air-water interface and transferred to silicon wafers using Langmuir-Schaefer deposition. Using layer-by-layer deposition, control on coating ...
متن کاملMFI zeolite nanosheets with post-synthetic Ti grafting for catalytic epoxidation of bulky olefins using H2O2.
The external surfaces of the surfactant-directed, 2.5 nm MFI zeolite nanosheets were grafted with Ti using titanium(IV) butoxide. The Ti/MFI nanosheets exhibited a remarkable catalytic performance for epoxidation of bulky olefins using H2O2 as an oxidant, in comparison to the mesoporous silicas with amorphous frameworks.
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ژورنال
عنوان ژورنال: Microscopy and Microanalysis
سال: 2016
ISSN: 1431-9276,1435-8115
DOI: 10.1017/s1431927616008928